Controlled ligand distortion and its outcomes for structure, symmetry, conformation and spin-state preferences regarding iron(ii) complexes. Exploring typically the reactivity of manganese(iii) processes with diphenolate-diamino ligands within rac-lactide polymerization. 1, 1′-Bis(di-tert-butylphosphino)ferrocene copper(i) complex catalyzed C-H activation and carboxylation of terminal alkynes.
An amine-functionalized metal organic framework for preferential CO( adsorption at low pressures. Generation associated with azomethine imine and metal-free formal 1, 3-dipolar cycloaddition of imine with PhIO: reaction, scope, and activity. Reactivity of the dimesityl-1, 8-naphthalenediylborate anion: isolation of the borataalkene isomer and synthesis of 1, 8-diborylnaphthalenes.
Rare-earth metal hydrides supported by silicon-bridged boratabenzene fluorenyl ligands: synthesis, structure and reactivity. Hard-and-soft phosphinoxide receptors with regard to f-element binding: structure plus photophysical properties of europium(iii) complexes. Substituent-controlled preference of carbonyl group-metal coordination inside d( metal complexes along with non-symmetric pentadentate ligands. Activity of Î³-amidine-functionalized dianionic Î²-diketiminato lanthanide amides and trianionic Î²-diketiminato Na/Sm heterobimetallic processes and their reactivity in polymerization of l-lactide. Structure-property relationships based on Hammett constants in cyclometalated iridium(iii) complexes: their application to be able to the design of a fluorine-free FIrPic-like emitter.
Versatile structures associated with group 13 metal halide complexes with 4, 4′-bipy: from 1D coordination polymers to 2D and 3 DIMENSIONAL metal-organic frameworks. New organic-inorganic hybrid compounds constructed through polyoxometalates and transition steel mixed-organic-ligand complexes. Synthesis in addition to structural characterization of monomeric mercury(ii) selenolate complexes derived from 2-phenylbenzamide ligands. Synthesis and reactivity of Li and TaMe3 complexes supported by N, N’-bis(2, 6-diisopropylphenyl)-o-phenylenediamido ligands.
Unprecedented flexibility of the particular 1, 1′-bis(o-carborane) ligand: catalytically-active species stabilised by B-agostic B-Hâ‡€Ru interactions. Metallamacrocycle development through dimerization of metal bioconjugates derived from amino acids and peptides. Activity of mono-, di-, and triaminobismuthanes and observation associated with C-C coupling of fragrant systems with bismuth(iii) chloride. Alkyl Grignard cross-coupling of aryl phosphates catalyzed simply by new, highly active ionic iron(ii) complexes containing a new phosphine ligand and a good imidazolium cation.
Hormone balance of the heavy group 15 elements with the pyridyl tethered 1, 2-bis(imino)acenaphthene “clamshell” ligand. Synthesis and characterisation of anionic and simple gallium(i) N-heterocyclic carbene pareils. Ethylene polymerisation and oligomerisation with arene-substituted phenoxy-imine things of titanium: investigation regarding multi-mechanism catalytic behaviour.
Rare earth metallic bis(silylamide) complexes bearing pyridyl-functionalized indenyl ligand: synthesis, structure and performance in the particular living polymerization of L-lactide and rac-lactide. Synthesis plus characterization of aryl tried bis(2-pyridyl)amines and their water piping olefin complexes: investigation of remote steric control above olefin binding. Copper(ii) processes of bis(aryl-imino)acenaphthene ligands: synthesis, structure, DFT studies plus evaluation in reverse ATRP of styrene.
- Structural snapshots in the copper(ii) induced azide-nitrile cycloaddition: effects regarding peripheral ligand substituents upon the formation of unsupported Î¼1, 1-azido vs. Î¼1, 4-tetrazolato bridged complexes.
- Palladium(ii) complexes with electron-poor, four, 5-disubstituted diimidazol-2-ylidene ligands: activity, characterization and catalytic exercise.
- Rare earth metal bis(silylamide) complexes bearing pyridyl-functionalized indenyl ligand: synthesis, structure and performance in the particular living polymerization of L-lactide and rac-lactide.
- Hydrogen bonded dimers of ketocoumarin in solid state and alcohol: drinking water binary solvent by fluorescence spectroscopy, crystal structure in addition to DFT investigation.
- Building five-membered heterocycle substituted phosphinous acids as ligands with regard to palladium-catalyzed Suzuki-Miyaura and Catellani reactions.
Controllable synthesis of Zn/Cd(ii) coordination polymers: dual-emissive luminescent properties, and tailoring release tendency under varying excitation energies. Transition metal (Rh and Fe) complexes and main-group (Se and B) adducts with N, N’-diphosphanyl NHC ligands: a review of stereoelectronic properties. Mixed-ligand copper(ii) Schiff base processes: the role of the co-ligand in DNA binding, DNA cleavage, protein binding plus cytotoxicity. Synthesis and skill chemistry of enamidophosphinimine scaffolds to generate diiron dinitrogen complexes.
Iron-catalysed homo- and copolymerisation of propylene: steric influence of bis(imino)pyridine ligands. Assessing the reactivity associated with sodium alkyl-magnesiates towards quinoxaline: single electron transfer (SET) vs. Amino group put together P/Ge and P/Sn Lewis pairs: synthesis and dipolar addition reactions to alkyne and aldehyde molecules. Synthetic, structural, and computational investigations of N-alkyl benzo-2, just one, 3-selenadiazolium iodides and their particular supramolecular aggregates.
Quenching regarding tryptophan fluorescence in numerous proteins by a series associated with small nickel complexes. Ni(ii), Pd(ii) and Pt(ii) processes of PNP and PSP tridentate amino-phosphine ligands. Bimetallic lanthanide amido complexes as highly active initiators with regard to the ring-opening polymerization associated with lactides.
Shaping and enforcing coordination spheres: probing the ability of tripodal ligands to favour trigonal refractive geometry. Novel pyrazolylphosphite- and pyrazolylphosphinite-ruthenium(ii) complexes as factors for hydrogenation of acetophenone. Copper-based energetic MOFs with 3-nitro-1H-1, 2, 4-triazole: solvent-dependent syntheses, structures and dynamic performances. Assembly of NHC-stabilized 2-hydrophosphasilenes from Si(iv) precursors: a Lewis acid-base complex. Carborane-stilbene dyads: the effect of substituents and cluster isomers on photoluminescence qualities.
Synthesis, characterization and reactivity associated with potassium and barium complexes containing phosphane-borane stabilized methanides. Cyclometalated Pd(ii) and Ir(iii) 2-(4-bromophenyl)pyridine complexes with N-heterocyclic carbenes (NHCs) and acetylacetonate (acac): synthesis, structures, luminescent properties and application in one-pot oxidation/Suzuki coupling of aryl chlorides containing hydroxymethyl. Iron(iii) complexes of multidentate pyridinyl ligands: synthesis, portrayal and catalysis from the direct hydroxylation of benzene.